A nuclear explosion is measured in Kilo-tons and extrapolated up to Mega-tons of TNT equivalent.
They know these figures because they actually detonated thousands of tons of TNT to see what happened. I think that those might be the biggest non-nuclear explosions.
When is comes to accidental explosions I believe that the Texas City disaster of 1947 is probably in there.
It involved 2300 tons of, yes guess what; Ammonium Nitrate which was on a ship in the port.
https://en.wikipedia.org/wiki/Texas_City_disaster
When stored as fertiliser in this country it has to have a retardant added.
When stored for prospective use to make explosive, by the addition of an accelerant, then all proper precautions for explosives must be in place.
The Captain of the MV Rhosus was already concerned at the volatility of his cargo in 2013, when he docked.
Since then it has been stored for six years in polypropylene bulk bags in a hot warehouse with no proper monitoring.
It did not need a catalyst, just a detonator, which in this case seems to have been a hot steel warehouse wall from a fire next door.